SYNTHESIS AND CHARACTERIZATION OF ZnO NANOPARTICLES FOR POTENTIAL APPLICATION IN LATENT FINGERPRINT DEVELOPMENT

Main Article Content

Atul Kumar Dubey
Praveen Pradhan
Maninder Kaur
Deepika Bhandari
Rohini Dharela
Dushyant Kumar

Keywords

Criminal investigations, Latent fingerprint, FE-SEM, XRD, ZnO nanoparticles

Abstract

The presentresearch work includes the synthesis and characterization of zinc oxide (ZnO) nanoparticles and their utilization for the development of latent fingerprint development. The synthesis of ZnO nanoparticles involves an economical precipitation process using zinc acetate dihydrate [Zn(OOCCH3)2.2H2O] and ethylene glycol (C2H6O2) as precursors.The structural examination of synthesized nanoparticles was done by employingField Emission ScanningElectron Microscopy (FE-SEM) and particle size analysis which showed that the nanoparticles formed were primarily hexagonal shaped and had an average size of up to 100 nm. The crystalline nature of the nanoparticleswas further verified by X-ray diffraction (XRD) study which confirms the hexagonal wurtzite structure of ZnO. These nanoparticles were then investigated as potential candidates for the development of latent fingerprints by testing them on various surfaces. From these studies, it has been observed that these nanoparticles helped in improving contrast and visibility, of the latent fingerprints, thereby helping in their effective revealing. The encouraging outcomes of the present work would be helpful asaprospective application of the synthesized ZnO nanoparticles in forensic research. Improvements in fingerprint detection methods could result from more optimization and analysis of their qualities, which would help law enforcement with criminal investigations.

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References

1. Hoover, J. Edgar. “fingerprint”. Encyclopedia Britannica, 9 Jan. 2024. Accessed 14 March 2024.
2. Nagar V, Tripathi K, Aseri V, Mavry B, Chopade R, Verma R, Singh A, Sankhla M S, Pritam P, Parihar K. (2022). Latent friction ridge analysis of developed fingerprints after treatment with various liquid materials on porous surface. Materialstoday. 69 (4), 1532-1539.
3. Lee HC, Gaensslen RE. Advances in fingerprint technology. 2nd ed. Washington, DC: CRC Press; 2001.
4. Cadd, S., Islam, M., Manson, P., Bleay, S. (2015). Fingerprint composition and aging: A literature review. Science & Justice, 55, 219–238.
5. Prabakaran, E., Pillay, K. (2021). Nanomaterials for latent fingerprint detection—A review. Journal of Materials Research and Technology, 12(5–6), 1856–1885.
6. Steiner, R., Roux, C., Moret, S. (2019). Controlling fingermark variability for research purposes: A review. WIREs Forensic Science, 1(4), e1338.
7. Chen YF. Forensic applications of nanotechnology. J Chin Chem Soc 2011;58:828–35.
8. Buzea C, Blandino IIP, Robbie K. Nanomaterials and nanoparticles: sources and toxicity. Biointerphases 2007;2(4):17–72.
9. Pudukudy, M., Yaakob, Z. (2015). Facile Synthesis of Quasi Spherical ZnO Nanoparticles with Excellent Photo catalytic Activity. Journal of cluster science. 26. 1187-1201.
10. Hossain, M. A., Islam, S. (2013). Synthesis of carbon nanoparticles from kerosene and their characterization by SEM/EDX, XRD and FTIR. American Journal of Nanoscience and Nanotechnology. 1(2): 52-56.
11. Mehta, B.K., Chhajlani, M., Shrivastava, B. D. (2017). Green synthesis of silver nanoparticles and their characterization by XRD. Journal of Physics: Conference Series. 836.
12. Mohan, A. C., Renjanadevi, B. (2016). Preparation of Zinc Oxide Nanoparticles and its Characterization Using Scanning Electron Microscopy (SEM) and X-Ray Diffraction (XRD). Procedia Technology. 24: 761-766.
13. Akbari, B., Tavandasti, M. P., Zandrahimi, M. (2011). Particle Size Characterization of Nanoparticles – A Practical approach. Iranian Journal of Materials Science & Engineering. 8(2): 48-56.
14. Yan, W., Petkov, V., Mahurin, S. M., Overburry, S. H., Dai, S. (2005). Powder XRD analysis and catalysis characterization of ultra-small gold nanoparticles deposited on titania-modified SBA-15. Catalysis Communications. 6(6): 404-408.
15. Sun, Y., Li, X., Cao, J., Zhang, W., Wang, H. P. (2006). Characterization of zero-valent iron nanoparticles. Advances in Colloid and Interface Science. 120(1-3): 47-56.
16. Baudot, C., Tan, C. M., Kong, J. C. (2010). FTIR spectroscopy as a tool for nano-material characterization. Infrared Physics & Technology. 53(6): 434-438.
17. Eid, M. M. (2022). Characterization of Nanoparticles by FTIR and FTIR-Microscopy. Handbook of consumer nanoproducts.
18. Petit, T., Puskar, L. (2018). FTIR spectroscopy of nanodiamonds: Methods and interpretation. Diamond and Related Materials. 89: 52-66.
19. Baraton, M. I., Merhari, L. (2007). Dual contribution of FTIR spectroscopy to nanoparticles characterization: surface chemistry and electrical properties. Proceeding SPIE. 6768. Nanomaterials Synthesis, Interfacing, and Integrating in Devices, Circuits, and Systems II, 676806.
20. Tannenbaum, R., Zubris, M., David, K., Ciprari, D., Jacob, K.,Jasiuk, I., Dan, N. (2006). FTIR Characterization of the Reactive Interface of Cobalt Oxide Nanoparticles Embedded in Polymeric Matrices. The Journal of Physical Chemistry B. 110(5): 2227-2232.
21. Yang, K., Peng, H., Wen, Y., Li, N. (2010). Re-examination of characteristic FTIR spectrum of secondary layer in bilayer oleic acid-coated Fe3O4 nanoparticles. Applied Surface Science. 256(10): 3093-3097.
22. Diaconu, M., Tache, A., Eremia, S. A. V., Gatea, F., Litescu, S., Radu, G. L. (2010). U. P. B. Scientific Bulletin. Series B. 72(3): 115-122.
23. Petreanu, I., Niculescu, V. C., Enache, S., Lacob, C. (2022). Structural Characterization of Silica and Amino-Silica Nanoparticles by Fourier Transform Infrared (FTIR) and Raman Spectroscopy. Analytical letters. Proceedings of the Thirteenth International Conference on Processes in Isotopes and Molecules (PIM 2021). 56(2): 390-403.
24. Ivan, Z., Mehmet, P., Emre, K., Dimka, I., Ivania, M., Ludmil, F. (2017). FTIR Spectroscopy Method For Investigation Of Co-Ni Nanoparticle Nanosurface Phenomena. Journal of Chemical Technology & Metallurgy. 52(5): 916.
25. Shukla, N., Liu, C., Jones, P. M., Weller, D. (2003). FTIR study of surfactant bonding to FePt nanoparticles. Journal of Magnetism and Magnetic Materials. 266(1-2); 178-184.
26. Titus, D., Samuel, E. J. J., Roopan, S. M. (2019). Chapter 12 - Nanoparticle characterization techniques. Green Synthesis, Characterization and Applications of Nanoparticles. Micro and Nano Technologies. 302-319.
27. Hossain, M. A., Islam, S. (2013). Synthesis of carbon nanoparticles from kerosene and their characterization by SEM/EDX, XRD and FTIR. American Journal of Nanoscience and Nanotechnology. 1(2): 52-56.
28. Sharma, S., Rasool, H. I., Palanisamy, V., Methisen, C., Schmidt, M., Wong, D. T., Gimzewski, J. K. (2010). Structural-Mechanical Characterization of Nanoparticle Exosomes in Human Saliva, Using Correlative AFM, FESEM, and Force Spectroscopy. ACSNano. 4(4). 1921-1926.
29. Nallusamy, S., Babu, A. M. (2015). X-Ray Differaction and FESEM Analysis for Mixture of Hybrid Nanoparticles in Heat Transfer Applications. Journal of Nano Research. 37: 58-67.
30. Takai, Z. I., Mustafa, M. K., Asman, S., Sekak, K. A. (2019). Preparation and Characterization of Magnetite (Fe3O4) nanoparticles By Sol-Gel Method. International Journal of Nanoelectronics and Materials. 12(1): 37-46.
31. Mishra, D., Arora, R., Lahiri, S., Amritphale. S. S., Chandra, N. (2014). Synthesis and characterization of iron oxide nanoparticles by solvothermal method. Protection of Metals and Physical Chemistry of Surface. 50: 628–631.
32. Ang, B.C., Yacoob, I. I., Nurdin, I. (2013). Investigation of Fe2O3/SiO2 Nanocomposite by FESEM and TEM. Journal of Nanomaterials. 2013(1).
33. Govindan, S., Nivethaa, E. A. K., Saravanan, R., Narayanan, V., Stephen, A. (2012). Synthesis and characterization of chitosan–silver nanocomposite. Applied Nanosciences. 2: 299-303.
34. Rajakumar, G., Rahuman, A. A., Priyamvada, V., Khanna, V. G., Kumar, D. K., Sujin, P. J. (2012). Ecliptaprostrata leaf aqueous extract mediated synthesis of titanium dioxide nanoparticles. Materials letters. 68: 115-117.
35. Sari, S., Qalbiah, U., Putri, I. (2018). Comparison between Latent Fingerprint Identification using Black Powder and Cyanoacrylate Glue. Asian Journal of Chemistry, 30, 2615-2620.
36. Garg R K, Kumari H, Kaur R. (2011). A new technique for visualization of latent fingerprints on various surfaces using powder from turmeric: A rhizomatous herbaceous plant (Curcuma longa). Egyptian Journal of Forensic Science. 1(1), 53-57.
37. Qiu Z, Hao B, Gu X, Wang Z, Xie N, Lam J, Hao H, Tang B Z. (2018). A general powder dusting method for latent fingerprint development based on AIEgens. Science China Chemistry. 61, 966-970.